To see step by step instructions with screenshots on how you decommission the last Exchange 2000/2003 server in the Exchange 2007 organization, you might also want to checkout this articles series:
http://www.msexchange.org/tutorials/Transitioning-Exchange-2000-2003-Exchange-Server-2007-Part1.html
http://www.msexchange.org/tutorials/Transitioning-Exchange-2000-2003-Exchange-Server-2007-Part2.html
http://www.msexchange.org/tutorials/Transitioning-Exchange-2000-2003-Exchange-Server-2007-Part3.html