The following will help you get started and continue with each of the System Center 2012 solution.

 

App Controller

http://blogs.technet.com/b/server-cloud/archive/2011/10/28/app-controller-enabling-application-self-service.aspx

http://technet.microsoft.com/en-us/library/hh546834.aspx

 

Configuration Manager

http://www.microsoft.com/en-us/server-cloud/system-center/configuration-manager-2012.aspx

http://technet.microsoft.com/en-us/library/gg682041.aspx

 

Data Protection Manager

http://www.microsoft.com/en-us/server-cloud/system-center/data-protection-manager.aspx

http://technet.microsoft.com/en-us/library/hh758173.aspx

 

Operations Manager

http://www.microsoft.com/en-us/server-cloud/system-center/operations-manager.aspx

http://technet.microsoft.com/en-us/library/hh205987.aspx

http://media.ch9.ms/teched/na/2011/ppt/SIM355.pptx

http://systemcenter.pinpoint.microsoft.com/en-US/home

 

Orchestrator

http://www.microsoft.com/en-us/server-cloud/system-center/opalis.aspx

http://technet.microsoft.com/en-us/library/hh237242.aspx

http://technet.microsoft.com/en-us/edge/Video/hh509042

http://media.ch9.ms/teched/na/2011/ppt/SIM207.pptx

http://www.microsoft.com/en-us/showcase/details.aspx?uuid=e965776e-8052-4337-8913-b374f251ba58

http://www.windowsitpro.com/article/system-center/understanding-system-center-orchestrator-2012-141144

http://orchestrator.codeplex.com/

IP - http://systemcenter.pinpoint.microsoft.com/en-US/applications/system-center-orchestrator-2012-release-candidate-integration-packs-12884928230

 

Service Manager

http://technet.microsoft.com/en-us/library/hh305220.aspx

http://social.technet.microsoft.com/wiki/contents/articles/8113.system-center-2012-service-manager-survival-guide.aspx

http://scug.be/blogs/scsm/archive/2011/05/02/system-center-service-manager-information-blog-overview.aspx

 

Unified Installer

http://technet.microsoft.com/en-us/library/hh751266.aspx

http://technet.microsoft.com/en-us/library/hh751290.aspx

 

Virtual Machine Manager

http://technet.microsoft.com/en-us/library/gg610610.aspx

http://blogs.technet.com/b/kevinholman/archive/2011/09/30/scvmm-2012-quickstart-deployment-guide.aspx

 

Good link to help you on your learning:

http://www.MicrosoftVirtualAcademy.com