Script Download: ExploreStartFolder(PowerShell).zip
http://gallery.technet.microsoft.com/scriptcenter/Change-Windows-Explorers-ac858780

The script shows how to change Windows Explorer’s (in taskbar) Starting Location in Windows 8.

When you start 'Windows Explorer (in taskbar)',it will navigate to 'Library' by default. However, sometimes people want it to navigate folder or 'Computer’. This script can achieve that. And I think it will be more convenient if set 'Windows Explorer' starting with folder often used.

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You can find more All-In-One Script Framework script samples at http://aka.ms/onescriptingallery