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KB Article: http://support.microsoft.com/kb/2589404
INTRODUCTION
Assume that you use the Send as Attachment command in a Microsoft Office 2010 application to send a file.When you type the name of a receiver in the To field, the AutoComplete feature does not function as expected in Microsoft Outlook 2010.Note This issue occurs when you use the Send as Attachment command in the Office 2010 application before Outlook 2010 is running.
Scratching my head. Does the hotfix mentioned in the KB fix the problem [as well as the FixIt] or both have to be applied?