根據Userenv log

Found file system path of:  <\\msft.com\sysvol\topsnmq.chtn.com.tw\Policies\{31B2F340-016D-11D2-945F-00C04FB984F9}>
USERENV(154.3c8) 10:12:20:687 ProcessGPO:  Couldn't find the group policy template file <\\msft.com\sysvol\msft.com\Policies\{31B2F340-016D-11D2-945F-00C04FB984F9}\gpt.ini>, error = 0x35.
USERENV(154.3c8) 10:12:20:718 ProcessGPO:  ==============================
USERENV(154.3c8) 10:12:20:718 EvalList:  ProcessGPO failed
USERENV(154.3c8) 10:12:20:718 GetGPOInfo:  EvaluateDeferredGPOs failed. Exiting
USERENV(154.3c8) 10:12:20:734 GetGPOInfo:  Leaving with 0
USERENV(154.3c8) 10:12:20:734 GetGPOInfo:  ********************************
USERENV(154.3c8) 10:12:20:734 ProcessGPOs: GetGPOInfo failed.
USERENV(154.3c8) 10:12:20:734 LeaveCriticalPolicySection: Critical section 0x428 has been released.
USERENV(154.3c8) 10:12:20:734 ProcessGPOs: Computer Group Policy has been applied.

徵狀

-由用戶端嘗試存取Server仍出現錯誤 "Windows 找不到檔案或項目"

-\\電腦名稱 可以正常存取,但是\\msft.com 存取會失敗

解決

檢察DC上的 TCP/IP netbios help service 沒有啟動, 啟動服務後 sysvol即可以正常存取,並且GPO可以套用成功